NUI
No nā nīnau e pili ana i kā mākou huahana a i ʻole ka papa inoa kumukūʻai, e ʻoluʻolu e waiho i kāu leka uila iā mākou a e hoʻopili mākou i loko o 24 mau hola.
NINAU ANOKūlana halihali
Hiki ke lawe ʻia ma ka wela maʻamau.
Manaʻo i ke ʻano hoʻouna
ma ka lewa, ma ka aina a ma ke kai paha
Kūlana mālama:
2-8 ° C, pono e mālama ʻia i loko o kahi kūlana i hoʻopaʻa ʻia, anu a me ka lā ʻole.
ola mālama
ma kahi o 2 makahiki
Ka nui o ke kauoha liʻiliʻi:
1kg (kūkākūkā)
palapala hōʻoia:COA, wahi hehee, Hoʻololi kikoʻī [α]D20 E hoʻouna mākou i nā ʻikepili āu e makemake ai.Akā no nā huahana maʻamau, hoʻouna mākou i ka ʻikepili hou ma hope o ka puka ʻana mai.
ʻOiaʻiʻo, hiki iā ʻoe ke ʻike i ka ʻikepili ma mua ma ke ʻano he kuhikuhi.
ZL-asparticacidα-benzylester;
CBZ-ASP-OBZL;
N-Benzyloxycarbonyl-L-asparticacidALPHA-benzylester;
ZL-ASPARTICACIDA-BENZYLESTER;
N-[(PHENYLMETHOXY)CARBONYL]-L-ASPARTICACID1-(PHENYLMETHYL)ESTER;
Cbz-Asp-OBZL-OH,(S)-4-(benzyloxy)-3-(benzyloxycarbonylamino)-4-oxobutanoicacid;
CBZ-L-ASP-ALPHA-BENZYLESTER;
CBZ-L-ASPARTICACIDA-BENZYLESTER
Hoʻohana pinepine ʻia lākou no ka hoʻopili ʻana i ka pauka.Pili ia i nā koi o nā mea kūʻai aku.No laila, e haʻi mai iā mākou i kāu koi ma mua o ka hoʻopaʻa ʻana inā loaʻa iā ʻoe nā noi kūikawā.
1kg a 25kg He paʻakikī ka paʻi waho.A he mea paʻakikī ke ʻoki a hōʻino.Hiki iā ia ke pale pono i kāu mau huahana.
Hana ʻia ʻo Ester mai ka hopena esterization o ka waika inorganic a i ʻole ka waikawa organik a i ʻole ka waiʻona.Hiki i ka waiʻona a i ʻole phenol a i ʻole acidic anhydride, ka waiʻona a me ka ethylene, ka ʻakika ʻakika manuahi a me nā derivatives momona momona hiki ke hoʻohua i ka ester.ʻO ka hydrogen ma ka alpha-carbon i loko o nā molekala ester e nalowale i ka waiʻona molekala me kahi ester molekala ʻē aʻe ma lalo o nā kūlana alkaline e hoʻohua ai i ka ester β-keto, i kapa ʻia ʻo ester contraction reaction.No ka laʻana, hana ʻia ka acetyl acetate e hana i ka acetyl ethyl acetate.He mea koʻikoʻi kēia pane i ka synthesis organik.
ʻO ka inoa o ka ester mai ka inoa like o ka waikawa carboxylic a me ka waiʻona a i ʻole phenol, e like me "kahi waikawa a me kekahi ester".Ua kapa ʻia nā esters pōʻai he lactone (lactone).ʻO nā waiwai kemika o ka ester ua like ia me ka amyl niche anhydride, ka mea maʻalahi i ka hydrolysis, ka waiʻona a me ka hopena amonia.ʻO ka ester haʻahaʻa haʻahaʻa he wai ʻala a me ka ʻole o ka waihoʻoluʻu, a paʻa ka ester kiʻekiʻe.ʻO Estes nā mea hoʻoheheʻe koʻikoʻi a me nā mea waiwai synthetic, a ʻo kekahi mau esters he lāʻau lapaʻau ponoʻī.E like me ke ʻano o ka waika, hiki ke hoʻokaʻawale ʻia ka ester i ka ester acid inorganic a me ka ester acid organic.ʻO Etate, he ester momona ka ethyl acetate, he ester aromatic ka acetate, a he ester cyclic ka namanonate.
He wai waihoʻoluʻu ʻole ka ester.ʻO ka ester i hana ʻia e ka lāhui momona a me ka waiʻona momona he ʻala hua, hiki ke hoʻoheheʻe ʻia i ka wai, a paʻakikī hoʻi e hoʻoheheʻe i ka wai.He haʻahaʻa ke kiko uila o kekahi ester a puhi pinepine.Hiki ke hoʻopili ʻia ka mahu e ka ʻōpū hanu, a hiki ke hoʻopili ʻia ka ester wai e ka ʻili.Ma hope o ka absorption, ua hoʻoheheʻe ʻia i loko o ka plasma, a hoʻokuʻu ʻia kekahi o lākou ma o nā māmā a me nā puʻupaʻa.Ma hope o kekahi hydrolysis, huli i ke kaʻina metabolic maʻamau.Ma waho aʻe o kekahi o nā pūhui ester, ʻo ka hapa nui o lākou he mea ʻawaʻawa a ʻona loa, a ʻo ka hapa nui o lākou he micro-toxic a hiki i nā ʻano mea ʻawaʻawa waena, a ʻo ka hapa nui o lākou he mea ʻona ʻole.Aia he 38 esters i loko o nā hui ʻala o ke kī.ʻO ka mea nui: ① ester momona: hana ʻia e ka waiʻona a me ka momona, e like me ka ethyl acetate, hexyl hexyate.② Aromatic ester: hana ʻia e ka waiʻona a me ka ʻakika ʻala, e like me Shun-3-hexylzyl.③ Circin esters: hana ʻia e ka waiʻona a me ka cyclocar, e like me ka jasmone hyacxide.ʻAʻole kūʻokoʻa ka ester, hiki ke hydrolyzed a hana i ka waiʻona a me ka waikawa.ʻO nā helu kalapona haʻahaʻa he mau wai ʻala, a ʻo nā helu kalapona kiʻekiʻe he wai a paʻa ʻole hiki ke hoʻoheheʻe ʻia i ka wai.
HL-Asp-OH | HD-Asp-OH | DL-Asp | HL-Asp(OBzl)-NCA |
HL-ASP(OBZL)-OTBU.HCl | HL-Asp(OBzl)-OBzl.HCl | L-Asp(Otbu)-Obzl.Hcl | HD-Asp-OBzl |
Asp(Obzl) | HL-Asp(OBzl)-OH | HD-Asp(OBzl)-OH | HL-Asp(OBzl)-OBzl•TosOH |
HL-Asp-OBzl | Asp(Obzl)2 | DL-Asp(Obzl)-Obzl | Boc-D-Asp(OBzl)-OH |
Boc-D-Asp-OBzl | Fmoc-L-Asp-Obzl | Cbz-D-Asp(Obzl) | Cbz-L-Asp(obzl)-Obzl |
1. No ka MOQ: Hiki iā mākou ke hoʻololi e like me kāu koi.
2. E pili ana i ka hāpana: Pono ka hāpana i ka uku hōʻailona, hiki ke lawe i ka ukana e hōʻiliʻili aiʻole hiki iāʻoe ke uku iā mākou ma mua.
3. Mold workshop, hiki ke hoʻopilikino ʻia e like me ka helu o nā hiʻohiʻona.
4. Hāʻawi mākou i ka lawelawe maikaʻi loa.Ke hana nei kekahi hui kūʻai akamai iā ʻoe.
5. E pili ana i ka hoʻololi: E ʻoluʻolu e leka uila a kamaʻilio mai iaʻu ma kou ʻoluʻolu.